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The model reaction between methyl 2-fluoropropionate Chemical substances/Nomenclature
and methoxide or hydroxide anion was studied at the PM3 
or ab initio 6-31G(d) SCF-MO levels respectively.... Chemical terminology
It can be envisaged that in the anti  transition state 
there is an n-s* stabilising  interaction of the 
Ahn-Eisenstein type, between the Chemical terminology
active site serine hydroxide nucleophile of the enzyme Biochemical terminology
and the low energy s*  orbital Chemical terminology
anti-periplanar to the C-F bond of the substrate.
 
SVG rather than  Bitmap  Chemical substance/reactions

The calculated PM3 entropy difference between 1 and 2  Relational terminology
of 0.4 cal K-1 mol-1  results in a free 
energy difference of 2.5 kcal mol-1 at 300K. STM Units
Published as HTML in J. Chem. Soc., Perkin Trans 2, 1994, 3. (c) Royal Society of Chemistry

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